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Chemical Communications
Urgent high quality communications from across the chemical sciences.
Chemical Communications,
07 January 2012
Ross Inglis, Constantinos J. Milios, Leigh F. Jones, Stergios Piligkos and Euan K. Brechin
Chem. Commun., 2012,&48, 181-190
DOI: 10.558A,
Feature Article
[MnIII6] and [MnIII3] complexes can have their magnetic behaviour changed via structural distortion and be used as building blocks for the construction of discrete and infinite architectures.
Peng Liu, Shuai Zhang, Mei-sha Chen, Qian Liu, Chenxuan Wang, Chen Wang, Yan-Mei Li, Flemming Besenbacher and Mingdong Dong
Chem. Commun., 2012,&48, 191-193
DOI: 10.285B,
Communication
The pathogenesis of type II diabetes can be linked to cosecreted hIAPP/insulin interacting with cell membranes. Here we investigate the nanostructures by co-assembling hIAPP and insulin on surfaces.
Liang Cui, Xiaoyan Lin, Ninghang Lin, Yanling Song, Zhi Zhu, Xi Chen and Chaoyong James Yang
Chem. Commun., 2012,&48, 194-196
DOI: 10.412E,
Communication
Based on graphene oxide-protected DNA probes, we have developed a cyclic enzymatic amplification method for sensitive and multiplex analysis of miRNAs in complex biological samples.
Bin Zhang, Yan Zhang and Daoben Zhu
Chem. Commun., 2012,&48, 197-199
DOI: 10.227K,
Communication
An organic–inorganic hybrid combining a semiconducting BEDT-TTF layer and a Jahn–Teller distorted oxalato-bridged honeycomb antiferromagnetic layer [Cu2(C2O4)32-]n was obtained and characterized.
Marie-Pierre Santoni, Amlan K. Pal, Garry S. Hanan, Marie-Christine Tang, Karine Venne, Alexandra Furtos, Pierre Ménard-Tremblay, Cédric Malveau and Bernold Hasenknopf
Chem. Commun., 2012,&48, 200-202
DOI: 10.155E,
Communication
Combining the geometric requirements of coordination complexes with functionalized polyoxometalates yields a designed self-assembled architecture.
Ashish Thakur, Kainan Zhang and Janis Louie
Chem. Commun., 2012,&48, 203-205
DOI: 10.990A,
Communication
From themed collection
A protocol based on a Pd(OAc)2/SPhos catalyst system for the Suzuki-Miyaura coupling of heteroaryl boronic acids and vinyl chlorides that minimizes protodeboronation is described.
Anu N. Amin, Mohamed E. El-Khouly, Navaneetha K. Subbaiyan, Melvin E. Zandler, Shunichi Fukuzumi and Francis D'Souza
Chem. Commun., 2012,&48, 206-208
DOI: 10.071K,
Communication
From themed collection
The first example of a BF2 chelated azadipyrromethene–fullerene dyad and the photoinduced electron transfer originating in this dyad are reported.
Rony S. Khnayzer, J?rg Blumhoff, Jordan A. Harrington, Alexandre Haefele, Fan Deng and Felix N. Castellano
Chem. Commun., 2012,&48, 209-211
DOI: 10.015J,
Communication
Upconversion photochemistry successfully sensitizes wide bandgap nanostructured WO3 photoanodes to sub-bandgap non-coherent green photons at low power density.
J. P. Dacquin, A. F. Lee, C. Pirez and K. Wilson
Chem. Commun., 2012,&48, 212-214
DOI: 10.563K,
Communication
Increased mass transport and acid site accessibility within expanded pore SBA-15 sulfonic acid silicas significantly enhances activity in transesterification and esterification reactions for biodiesel synthesis.
Miguel Palomino, Avelino Corma, Jose L. Jordá, Fernando Rey and Susana Valencia
Chem. Commun., 2012,&48, 215-217
DOI: 10.320E,
Communication
Zeolite Rho: the best zeolite ever reported for performing selective separation of CO2 and CH4.
Yanjun Zhu, Dan A. Smith, David E. Herbert, Sylvain Gatard and Oleg V. Ozerov
Chem. Commun., 2012,&48, 218-220
DOI: 10.845G,
Communication
Oxidative addition of the phenyl–oxygen bond to a pincer-supported (PNP)Rh fragment is possible for certain phenyl carboxylates.
Hee Jung Lee, Won Cho and Moonhyun Oh
Chem. Commun., 2012,&48, 221-223
DOI: 10.213F,
Communication
The conjunction of porous ZIF-8 with polystyrene spheres is demonstrated to induce the formation of polystyrene@ZIF-8 core–shell structures. A subsequent etching process on polystyrene@ZIF-8 core–shells to remove polystyrene cores results in a unique hollow ZIF-8.
Yi-Ge Zhou, Neil V. Rees, Jeseelan Pillay, Robert Tshikhudo, Sibulelo Vilakazi and Richard G. Compton
Chem. Commun., 2012,&48, 224-226
DOI: 10.407D,
Communication
The electroactivity of gold nanoparticles is demonstrated and used for their characterisation via nanoparticle–electrode impacts.
Christian F?rber, Michael Leibold, Clemens Bruhn, Martin Maurer and Ulrich Siemeling
Chem. Commun., 2012,&48, 227-229
DOI: 10.460K,
Communication
A hitherto unrecognised NHC-type tautomer of the mesoionic compound Nitron has been uncovered through its reactions with carbene trapping reagents.
Jia Liu, Raymond Wai-Yin Sun, Chung-Hang Leung, Chun-Nam Lok and Chi-Ming Che
Chem. Commun., 2012,&48, 230-232
DOI: 10.317J,
Communication
Cyclometalated platinum(II) complexes [PtII(C∧N∧N)(CNR)]+ (HC∧N∧N = 6-phenyl-2,2′-bipyridyl) display significant inhibition towards TNF-α stimulated NF-κB-dependent gene transcription at concentrations down to the micromolar range.
Fuye Gao, Craig T. M. Stamp, Paul D. Thornton, T. Stanley Cameron, Lauren E. Doyle, David O. Miller and D. Jean Burnell
Chem. Commun., 2012,&48, 233-235
DOI: 10.452D,
Communication
From themed collection
Angular tricyclic compounds with a variety of ring-sizes were produced by ring-rearrangement metathesis, sometimes with a high degree of selectivity.
Puchang Lie, Jie Liu, Zhiyuan Fang, Boying Dun and Lingwen Zeng
Chem. Commun., 2012,&48, 236-238
DOI: 10.878C,
Communication
A lateral flow biosensor based on isothermal strand-displacement polymerase reaction and gold nanoparticles has been developed for the visual detection of nucleic acids with a detection limit of 0.01 fM.
Ayano Kimoto, Kosei Yamauchi, Masaki Yoshida, Shigeyuki Masaoka and Ken Sakai
Chem. Commun., 2012,&48, 239-241
DOI: 10.109F,
Communication
From themed collection
The RuVO species and other intermediates in O2 evolution from water catalyzed by [Ru(terpy)(bpy)(OH2)]2+ were spectrophotometrically characterized, and the spectral components observed were identified based on the TD-DFT calculations.
Xiaopeng Qi, Guangwei She, Yunyu Liu, Lixuan Mu and Wensheng Shi
Chem. Commun., 2012,&48, 242-244
DOI: 10.674H,
Communication
CdS/ZnO nanotube arrays with excellent photoelectrochemical properties were synthesized by a facile electrochemical method.
Yan Liang, Biao Kong, Anwei Zhu, Zhen Wang and Yang Tian
Chem. Commun., 2012,&48, 245-247
DOI: 10.060E,
Communication
A selective and sensitive photoelectrochemical strategy for determination of Cd2+ has been developed based on in situ electrodeposition of CdSe clusters on TiO2 nanotubes.
Arindam Modak, Mahasweta Nandi, John Mondal and Asim Bhaumik
Chem. Commun., 2012,&48, 248-250
DOI: 10.275E,
Communication
A new series of porphyrin based porous organic polymers has been synthesized using an extended aromatic substitution reaction between pyrrole and aromatic di-aldehydes and the materials have very high BET surface areas and excellent CO2 capture (~19 wt%) property.
Xuefeng Zhu, Huanying Liu, You Cong and Weishen Yang
Chem. Commun., 2012,&48, 251-253
DOI: 10.631J,
Communication
Dual-phase membranes, Ce0.8Sm0.2O1.9–Sm1-x(Ca)xMn0.5Co0.5O3, showing high oxygen permeation fluxes and stability under a CO2 environment are promising materials for CO2 capture via an oxyfuel route.
Qian-Rong Fang, Da-Qiang Yuan, Julian Sculley, Wei-Gang Lu and Hong-Cai Zhou
Chem. Commun., 2012,&48, 254-256
DOI: 10.687J,
Communication
A stable MOF with two types of mesoporous cages has been presented, and it exhibits a marked N2, O2, Ar and H2 hysteretic behaviour.
Sungeun Yang, Na-Young Park, Joung Woo Han, Cheonghee Kim, Seung-Cheol Lee and Hyunjoo Lee
Chem. Commun., 2012,&48, 257-259
DOI: 10.204G,
Communication
Platinum tended to deposit as layers on the octahedral gold nanocrystals with an Au(111) surface, while it aggregated and formed small particles on the cubic gold nanocrystals with an Au(100) surface.
Qingsheng Gao, Sinong Wang, Yi Tang and Cristina Giordano
Chem. Commun., 2012,&48, 260-262
DOI: 10.642J,
Communication
Fe–MoOx/polyaniline nanorods were fabricated via in situ polymerization, which exhibited high performance in epoxidation due to the hybrid structure and Fe3+-additive.
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176 citations
A collaborative sensitization by silyl-anchor and carboxy-anchor dyes (ADEKA-1 + LEG4) in dye-sensitized solar cells realized a high light-to-electric energy conversion efficiency of over 14% under one sun illumination.
DOI: 10.759F
27 citations
This feature article discusses the rational control of nano-scale metal catalysts for catalytic biomass transformation.
DOI: 10.336B
89 citations
Neutron diffraction shows the methylammonium cation in the photovoltaic [CH3NH3]PbI3 demonstrates increasing positional disorder on heating from 100 K to 352 K.
DOI: 10.944C
69 citations
Spectrophotometric monitoring of nitrophenol reduction to aminophenol in the presence of nanoparticle catalysts becomes a universal reaction to test a nanocatalyst.
DOI: 10.131K
84 citations
Here we describe the various strategies for the synthesis of imidazo[1,2-a]pyridines.
DOI: 10.495K
43 citations
Cocrystals, a long known but understudied class of crystalline solids, have attracted interest from crystal engineers and pharmaceutical scientists in the past decade and are now an integral part of the preformulation stage of drug development.
DOI: 10.216A
29 citations
A simple and reproducible halide ion exchange method is reported, which can tune the optical properties in CsPbX3 (X = Cl, Br, and I) nanocrystals. CSPbI3 nanocrystals exhibit promising application in photodetectors.
DOI: 10.643D
58 citations
We investigate herein the 2H → 1T phase transition upon chemical exfoliation of the four most widely considered TMD materials: MoS2, MoSe2, WS2 and WSe2.
DOI: 10.803D
16 citations
The light-induced reaction of aryldiazonium salts with gold(i) chloride complexes provides an easy access to cationic or neutral arylgold(iii) complexes, even a bromoaryl group can be selectively installed at gold(iii), and either chelating or monodentate ligands can be used.
DOI: 10.199A
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